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Ligand-Free Pd(OAc)(2) Catalyzed Heck Reaction under Air
Chen, Wei1; Yu, Miao2; Pan, Delin3; Jiao, Ning3
关键词ligand-free Pd-catalyzed Heck reaction
刊名CHINESE JOURNAL OF ORGANIC CHEMISTRY
2010-03-01
30期:3页:469-473
收录类别SCI
文章类型Article
WOS标题词Science & Technology
类目[WOS]Chemistry, Organic
研究领域[WOS]Chemistry
关键词[WOS]HYDROGEN SUBSTITUTION-REACTIONS ; ELECTRON-RICH OLEFINS ; COUPLING REACTIONS ; ARYL CHLORIDES ; VINYL ETHERS ; C-C ; PALLADIUM ; HALIDES ; ARYLATION ; SYSTEM
英文摘要

Ligand-free Pd(OAc)(2) catalyzed Heck reaction under air was studied in this work. Iodobenzene, bromobenzene and their derivatives reacted smoothly with different alkenes in the presence of palladium acetate. The reactions were conducted under air in the absence of ligand. The effect of base, additives, solvents and catalysts on this transformation was investigated. The optimized reaction conditions were approved as: Pd(OAc)(2) (5 mol%), Ag2CO3 (0.6 equiv.), reflux in benzene or toluene under air.

语种中文
WOS记录号WOS:000276472100024
Citation statistics
Cited Times:4[WOS]   [WOS Record]     [Related Records in WOS]
文献类型期刊论文
条目标识符http://ir.bjmu.edu.cn/handle/400002259/63550
Collection北京大学药学院
北京大学药学院_天然药物与仿生药物国家重点实验室
作者单位1.Chinese PLA Postgrad Med Sch, Beijing 100853, Peoples R China
2.Chinese Peoples Liberat Army Gen Hosp, Dept Radiol, Beijing 100853, Peoples R China
3.Peking Univ, State Key Lab Nat & Biomimet Drugs, Sch Pharmaceut Sci, Beijing 100191, Peoples R China
Recommended Citation
GB/T 7714
Chen, Wei,Yu, Miao,Pan, Delin,et al. Ligand-Free Pd(OAc)(2) Catalyzed Heck Reaction under Air[J]. CHINESE JOURNAL OF ORGANIC CHEMISTRY,2010,30(3):469-473.
APA Chen, Wei,Yu, Miao,Pan, Delin,&Jiao, Ning.(2010).Ligand-Free Pd(OAc)(2) Catalyzed Heck Reaction under Air.CHINESE JOURNAL OF ORGANIC CHEMISTRY,30(3),469-473.
MLA Chen, Wei,et al."Ligand-Free Pd(OAc)(2) Catalyzed Heck Reaction under Air".CHINESE JOURNAL OF ORGANIC CHEMISTRY 30.3(2010):469-473.
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