IR@PKUHSC  > 北京大学药学院
学科主题药学
Active Cobalt Catalyst for the Cleavage of Benzyl Ether
Wang, Bo; Yin, Zhaojun; Li, Yangbing; Yang, Ting-Xiang; Meng, Xiang-Bao; Li, Zhong-Jun
刊名JOURNAL OF ORGANIC CHEMISTRY
2011-11-18
DOI10.1021/jo2018284
76期:22页:9531-9535
收录类别SCI ; IC ; CCR
文章类型Article
WOS标题词Science & Technology
类目[WOS]Chemistry, Organic
资助者National Natural Science Foundation of China ; National Basic Research Program of China ; National Natural Science Foundation of China ; National Basic Research Program of China
研究领域[WOS]Chemistry
关键词[WOS]DE-O-BENZYLATION ; 3,4-DIMETHOXYBENZYL PROTECTING GROUPS ; SELECTIVE HYDROGENOLYSIS ; MPM 4-METHOXYBENZYL ; RANEY-NICKEL ; EFFICIENT ; SYSTEM ; MONOSACCHARIDES ; DEPROTECTION ; REDUCTION
英文摘要

An improved method for the deprotection of benzyl ethers using a catalytic amount of Co-2(CO)(8) in the presence of Me2PhSiH and CO (1 atm) is described. The deprotection reaction is compatible with double bond or sulfur-containing substrates. The method also tolerates other functional groups, such as Ac, Piv, and Bz, and shows potential selectivity in perbenzylated monosaccharides.

语种英语
所属项目编号20732001 ; 21072016 ; 2012CB822100
资助者National Natural Science Foundation of China ; National Basic Research Program of China ; National Natural Science Foundation of China ; National Basic Research Program of China
WOS记录号WOS:000296754400039
Citation statistics
Cited Times:10[WOS]   [WOS Record]     [Related Records in WOS]
文献类型期刊论文
条目标识符http://ir.bjmu.edu.cn/handle/400002259/63860
Collection北京大学药学院
作者单位Peking Univ, State Key Lab Nat & Biomimet Drugs, Sch Pharmaceut Sci, Beijing 100191, Peoples R China
Recommended Citation
GB/T 7714
Wang, Bo,Yin, Zhaojun,Li, Yangbing,et al. Active Cobalt Catalyst for the Cleavage of Benzyl Ether[J]. JOURNAL OF ORGANIC CHEMISTRY,2011,76(22):9531-9535.
APA Wang, Bo,Yin, Zhaojun,Li, Yangbing,Yang, Ting-Xiang,Meng, Xiang-Bao,&Li, Zhong-Jun.(2011).Active Cobalt Catalyst for the Cleavage of Benzyl Ether.JOURNAL OF ORGANIC CHEMISTRY,76(22),9531-9535.
MLA Wang, Bo,et al."Active Cobalt Catalyst for the Cleavage of Benzyl Ether".JOURNAL OF ORGANIC CHEMISTRY 76.22(2011):9531-9535.
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