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Highly direct alpha-selective Glycosylations of 3,4-O-carbonate-protected 2-deoxy- and 2,6-dideoxythioglycosides by preactivation protocol
Lu, Yin-Suo; Li, Qin; Zhang, Li-He; Ye, Xin-Shan
刊名ORGANIC LETTERS
2008-08-21
DOI10.1021/ol801190c
10期:16页:3445-3448
收录类别SCI ; IC ; CCR
文章类型Article
WOS标题词Science & Technology
类目[WOS]Chemistry, Organic
研究领域[WOS]Chemistry
关键词[WOS]STEREOSELECTIVE-SYNTHESIS ; STEREOCONTROLLED SYNTHESIS ; OLIGOSACCHARIDE SYNTHESIS ; BETA-MANNOPYRANOSIDES ; SULFOXIDE METHOD ; DONORS ; 2-DEOXYGLYCOSIDES ; 2-DEOXY-BETA-GLYCOSIDES ; THIOGLYCOSIDES ; ACTIVATION
英文摘要

A new efficient pre-activation method for the highly alpha-stereoselective glycosylation of 2-deoxysugars and 2,6-dideoxysugars has been developed using 2-deoxy- and 2,6-dideoxythioglycosides as glycosyl donors. The approach allows a wide range of glycosyl acceptors and donors to be used; the alpha-selectivity is very good to excellent.

语种英语
WOS记录号WOS:000258293100017
引用统计
被引频次:32[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.bjmu.edu.cn/handle/400002259/64128
专题北京大学药学院
作者单位Peking Univ, Sch Pharmaceut Sci, State Key Lab Nat & Biomimet Drugs, Beijing 100080, Peoples R China
推荐引用方式
GB/T 7714
Lu, Yin-Suo,Li, Qin,Zhang, Li-He,et al. Highly direct alpha-selective Glycosylations of 3,4-O-carbonate-protected 2-deoxy- and 2,6-dideoxythioglycosides by preactivation protocol[J]. ORGANIC LETTERS,2008,10(16):3445-3448.
APA Lu, Yin-Suo,Li, Qin,Zhang, Li-He,&Ye, Xin-Shan.(2008).Highly direct alpha-selective Glycosylations of 3,4-O-carbonate-protected 2-deoxy- and 2,6-dideoxythioglycosides by preactivation protocol.ORGANIC LETTERS,10(16),3445-3448.
MLA Lu, Yin-Suo,et al."Highly direct alpha-selective Glycosylations of 3,4-O-carbonate-protected 2-deoxy- and 2,6-dideoxythioglycosides by preactivation protocol".ORGANIC LETTERS 10.16(2008):3445-3448.
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