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Copper-Catalyzed Aerobic Oxidative C-C Bond Cleavage for C-N Bond Formation: From Ketones to Amides
Tang, Conghui1; Jiao, Ning1,2
关键词amides cleavage reactions copper ketones oxygen
刊名ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
2014-06-01
DOI10.1002/anie.201403528
53期:25页:6528-6532
收录类别SCI ; CCR
文章类型Article
WOS标题词Science & Technology
类目[WOS]Chemistry, Multidisciplinary
研究领域[WOS]Chemistry
关键词[WOS]ALPHA-HYDROXYPHENYLACETIC ACIDS ; CARBON TRIPLE BOND ; ARYL ALKYL KETONES ; MOLECULAR-OXYGEN ; METAL-FREE ; ROOM-TEMPERATURE ; DIRECT TRANSFORMATION ; PHENYLACETIC ACIDS ; ALCOHOL OXIDATIONS ; ORGANIC-CHEMICALS
英文摘要

A novel copper-catalyzed aerobic oxidative C(CO)-C(alkyl) bond cleavage reaction of aryl alkyl ketones for C-N bond formation is described. A series of acetophenone derivatives as well as more challenging aryl ketones with long-chain alkyl substituents could be selectively cleaved and converted into the corresponding amides, which are frequently found in biologically active compounds and pharmaceuticals.

语种英语
WOS记录号WOS:000337095900040
引用统计
被引频次:97[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.bjmu.edu.cn/handle/400002259/65274
专题北京大学药学院
北京大学药学院_天然药物与仿生药物国家重点实验室
作者单位1.Peking Univ, Sch Pharmaceut Sci, State Key Lab Nat & Biomimet Drugs, Beijing 100191, Peoples R China
2.Chinese Acad Sci, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
推荐引用方式
GB/T 7714
Tang, Conghui,Jiao, Ning. Copper-Catalyzed Aerobic Oxidative C-C Bond Cleavage for C-N Bond Formation: From Ketones to Amides[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2014,53(25):6528-6532.
APA Tang, Conghui,&Jiao, Ning.(2014).Copper-Catalyzed Aerobic Oxidative C-C Bond Cleavage for C-N Bond Formation: From Ketones to Amides.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,53(25),6528-6532.
MLA Tang, Conghui,et al."Copper-Catalyzed Aerobic Oxidative C-C Bond Cleavage for C-N Bond Formation: From Ketones to Amides".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 53.25(2014):6528-6532.
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