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Transition Metal-Free Oxidative Radical Decarboxylation/Cyclization for the Construction of 6-Alkyl/Aryl Phenanthridines
Lu, Shichao1,2,3,4; Gong, Yaling3,4; Zhou, Demin1
刊名JOURNAL OF ORGANIC CHEMISTRY
2015-09-18
DOI10.1021/acs.joc.5b01518
80期:18页:9336-9341
收录类别SCI
文章类型Article
WOS标题词Science & Technology
类目[WOS]Chemistry, Organic
研究领域[WOS]Chemistry
关键词[WOS]C-BOND FORMATION ; ALIPHATIC CARBOXYLIC-ACIDS ; ALPHA-KETO ACIDS ; 6-SUBSTITUTED PHENANTHRIDINES ; DECARBOXYLATIVE ALKYNYLATION ; ISOCYANIDE INSERTION ; EFFICIENT SYNTHESIS ; DIRECT ARYLATION ; CYCLIZATION ; 2-ISOCYANOBIPHENYLS
英文摘要

A radical cascade decarboxylation/cyclization of 2-isocyanobiphenyls with aliphatic carboxylic acids as well as aromatic carboxylic acids under the transition metal-free conditions was reported. This process, which included formation of two new C-C bonds and cleavage of C-COOH bonds, afforded a novel and environmentally friendly approach to producing 6-alkyl/aryl phenanthridines with moderate to good yields.

语种英语
WOS记录号WOS:000361866700045
项目编号2014CB849600
资助机构Beijing Postdoctoral Research Foundation ; Ministry of Science and Technology, China
引用统计
被引频次:37[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.bjmu.edu.cn/handle/400002259/65355
专题北京大学药学院
作者单位1.Natl Inst Biol Sci, Beijing 102206, Peoples R China
2.Peking Univ, Sch Pharmaceut Sci, State Key Lab Nat & Biomimet Drugs, Beijing 100191, Peoples R China
3.Chinese Acad Med Sci, Inst Mat Med, Beijing 100050, Peoples R China
4.Peking Union Med Coll, Beijing 100050, Peoples R China
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GB/T 7714
Lu, Shichao,Gong, Yaling,Zhou, Demin. Transition Metal-Free Oxidative Radical Decarboxylation/Cyclization for the Construction of 6-Alkyl/Aryl Phenanthridines[J]. JOURNAL OF ORGANIC CHEMISTRY,2015,80(18):9336-9341.
APA Lu, Shichao,Gong, Yaling,&Zhou, Demin.(2015).Transition Metal-Free Oxidative Radical Decarboxylation/Cyclization for the Construction of 6-Alkyl/Aryl Phenanthridines.JOURNAL OF ORGANIC CHEMISTRY,80(18),9336-9341.
MLA Lu, Shichao,et al."Transition Metal-Free Oxidative Radical Decarboxylation/Cyclization for the Construction of 6-Alkyl/Aryl Phenanthridines".JOURNAL OF ORGANIC CHEMISTRY 80.18(2015):9336-9341.
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