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学科主题: 药学
题名:
Transition Metal-Free Oxidative Radical Decarboxylation/Cyclization for the Construction of 6-Alkyl/Aryl Phenanthridines
作者: Lu, Shichao1,2,3,4; Gong, Yaling3,4; Zhou, Demin1
刊名: JOURNAL OF ORGANIC CHEMISTRY
发表日期: 2015-09-18
DOI: 10.1021/acs.joc.5b01518
卷: 80, 期:18, 页:9336-9341
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
关键词[WOS]: C-BOND FORMATION ; ALIPHATIC CARBOXYLIC-ACIDS ; ALPHA-KETO ACIDS ; 6-SUBSTITUTED PHENANTHRIDINES ; DECARBOXYLATIVE ALKYNYLATION ; ISOCYANIDE INSERTION ; EFFICIENT SYNTHESIS ; DIRECT ARYLATION ; CYCLIZATION ; 2-ISOCYANOBIPHENYLS
英文摘要:

A radical cascade decarboxylation/cyclization of 2-isocyanobiphenyls with aliphatic carboxylic acids as well as aromatic carboxylic acids under the transition metal-free conditions was reported. This process, which included formation of two new C-C bonds and cleavage of C-COOH bonds, afforded a novel and environmentally friendly approach to producing 6-alkyl/aryl phenanthridines with moderate to good yields.

语种: 英语
所属项目编号: 2014CB849600
项目资助者: Beijing Postdoctoral Research Foundation ; Ministry of Science and Technology, China
WOS记录号: WOS:000361866700045
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.bjmu.edu.cn/handle/400002259/65355
Appears in Collections:北京大学药学院_期刊论文

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作者单位: 1.Natl Inst Biol Sci, Beijing 102206, Peoples R China
2.Peking Univ, Sch Pharmaceut Sci, State Key Lab Nat & Biomimet Drugs, Beijing 100191, Peoples R China
3.Chinese Acad Med Sci, Inst Mat Med, Beijing 100050, Peoples R China
4.Peking Union Med Coll, Beijing 100050, Peoples R China

Recommended Citation:
Lu, Shichao,Gong, Yaling,Zhou, Demin. Transition Metal-Free Oxidative Radical Decarboxylation/Cyclization for the Construction of 6-Alkyl/Aryl Phenanthridines[J]. JOURNAL OF ORGANIC CHEMISTRY,2015,80(18):9336-9341.
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