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2,4-vs 3,4-Disubsituted Pyrrole Synthesis Switched by Copper and Nickel Catalysts
Chen, Feng1; Shen, Tao1; Cui, Yuxin1; Jiao, Ning1,2
刊名ORGANIC LETTERS
2012-09-21
DOI10.1021/ol302270z
14期:18页:4926-4929
收录类别SCI ; IC ; CCR
文章类型Article
WOS标题词Science & Technology
类目[WOS]Chemistry, Organic
资助者National Basic Research Program of China (973 Program) ; National Science Foundation of China ; Peking University ; National Basic Research Program of China (973 Program) ; National Science Foundation of China ; Peking University
研究领域[WOS]Chemistry
关键词[WOS]VINYL AZIDES ; SUBSTITUTED PYRROLES ; 1,3-DICARBONYL COMPOUNDS ; C-H ; POLYSUBSTITUTED PYRROLES ; CONTAINING HETEROCYCLES ; EFFICIENT SYNTHESIS ; PHENACYL AZIDES ; DOMINO APPROACH ; DERIVATIVES
英文摘要

A novel and efficient copper or nickel catalyzed highly selective denitrogenative annulation of vinyl azides with aryl acetaldehydes has been developed. 2,4- and 3,4-diaryl substituted pyrroles, which are difficult to synthesize by the reported methods, can be highly regioselectively prepared by this protocol simply switched by the selection of the transition metal catalysts. Compared with the reported acidic or basic conditions for polysubstituted pyrrole synthesis, the present reaction conditions are mild, neutral, and very simple without any additives.

语种英语
所属项目编号2009CB825300 ; 21172006
资助者National Basic Research Program of China (973 Program) ; National Science Foundation of China ; Peking University ; National Basic Research Program of China (973 Program) ; National Science Foundation of China ; Peking University
WOS记录号WOS:000308958500057
Citation statistics
Cited Times:71[WOS]   [WOS Record]     [Related Records in WOS]
文献类型期刊论文
条目标识符http://ir.bjmu.edu.cn/handle/400002259/65557
Collection北京大学药学院
作者单位1.Peking Univ, Sch Pharmaceut Sci, State Key Lab Nat & Biomimet Drugs, Beijing 100191, Peoples R China
2.E China Normal Univ, Dept Chem, Shanghai Key Lab Green Chem & Chem Proc, Shanghai 200062, Peoples R China
Recommended Citation
GB/T 7714
Chen, Feng,Shen, Tao,Cui, Yuxin,et al. 2,4-vs 3,4-Disubsituted Pyrrole Synthesis Switched by Copper and Nickel Catalysts[J]. ORGANIC LETTERS,2012,14(18):4926-4929.
APA Chen, Feng,Shen, Tao,Cui, Yuxin,&Jiao, Ning.(2012).2,4-vs 3,4-Disubsituted Pyrrole Synthesis Switched by Copper and Nickel Catalysts.ORGANIC LETTERS,14(18),4926-4929.
MLA Chen, Feng,et al."2,4-vs 3,4-Disubsituted Pyrrole Synthesis Switched by Copper and Nickel Catalysts".ORGANIC LETTERS 14.18(2012):4926-4929.
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