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学科主题: 药学
题名:
Syntheses of lewis(x) and dimeric lewis(x): Construction of branched oligosaccharides by a combination of preactivation and reactivity based chemoselective one-pot Glycosylations
作者: Miermont, Adeline; Zeng, Youlin; Jing, Yuqing; Ye, Xin-Shan; Huang, Xuefei
刊名: JOURNAL OF ORGANIC CHEMISTRY
发表日期: 2007-11-09
DOI: 10.1021/jo701694k
卷: 72, 期:23, 页:8958-8961
收录类别: SCI ; IC ; CCR
文章类型: Article
WOS标题词: Science & Technology
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
关键词[WOS]: SOLID-PHASE SYNTHESIS ; ANTIGEN ; ADENOCARCINOMA ; DETERMINANT ; DERIVATIVES ; ACTIVATION ; ALCOHOLS ; DONORS
英文摘要:

[GRAPHICS]

Two asymmetrically branched oligosaccharides, Lewis′ and dimeric Lewis(X), were assembled in one pot with high yields and exclusive regio- and stereoselectivities. p-Tolyl thiogly-cosides were utilized as the sole type of building blocks, thus simplifying the overall synthetic design. The reactivity-independent nature of the preactivation based method allows modular assembly of the dimeric Lewis(X) octasaccharide without the need for tedious protective group manipulation to achieve exact anomeric reactivities.

语种: 英语
WOS记录号: WOS:000250681900047
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.bjmu.edu.cn/handle/400002259/66305
Appears in Collections:北京大学药学院_期刊论文

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作者单位: 1.Univ Toledo, Dept Chem, Toledo, OH 43606 USA
2.Peking Univ, Sch Pharmaceut Sci, State Key Lab Nat & Biomimet Drugs, Beijing 100083, Peoples R China

Recommended Citation:
Miermont, Adeline,Zeng, Youlin,Jing, Yuqing,et al. Syntheses of lewis(x) and dimeric lewis(x): Construction of branched oligosaccharides by a combination of preactivation and reactivity based chemoselective one-pot Glycosylations[J]. JOURNAL OF ORGANIC CHEMISTRY,2007,72(23):8958-8961.
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