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Bronsted acid mediated nitrogenation of propargylic alcohols: an efficient approach to alkenyl nitriles
Huang, Xiaoqiang1; Jiao, Ning1,2
刊名ORGANIC & BIOMOLECULAR CHEMISTRY
2014
DOI10.1039/c4ob00888j
12期:25页:4324-4328
收录类别SCI ; IC ; CCR
文章类型Article
WOS标题词Science & Technology
类目[WOS]Chemistry, Organic
研究领域[WOS]Chemistry
关键词[WOS]MEYER-SCHUSTER REARRANGEMENT ; ONE-POT SYNTHESIS ; CARBONYL-COMPOUNDS ; ALPHA,BETA-UNSATURATED NITRILES ; STEREOSELECTIVE-SYNTHESIS ; PRACTICAL SYNTHESIS ; DIRECT TRANSFORMATION ; ALLENYL AZIDES ; BOND FORMATION ; CATALYSIS
英文摘要

A novel and efficient approach to alkenyl nitriles from readily available propargylic alcohols has been developed. This nitrogenation reaction is transition-metal-free and could be conducted under air at ambient temperature, which makes this protocol promising and practical. Moreover, NH4Br is disclosed as an efficient additive to promote the stereoselectivity of this reaction.

语种英语
WOS记录号WOS:000337129000009
项目编号21325206 ; 21172006 ; 20120001110013
资助机构National Science Foundation of China ; National Young Topnotch Talent Support Program ; Ph.D. Programs Foundation of the Ministry of Education of China
引用统计
被引频次:19[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.bjmu.edu.cn/handle/400002259/66334
专题北京大学药学院
北京大学药学院_天然药物与仿生药物国家重点实验室
作者单位1.Peking Univ, Sch Pharmaceut Sci, State Key Lab Nat & Biomimet Drugs, Beijing 100191, Peoples R China
2.Nankai Univ, State Key Lab Elementoorgan Chem, Tianjin 300071, Peoples R China
推荐引用方式
GB/T 7714
Huang, Xiaoqiang,Jiao, Ning. Bronsted acid mediated nitrogenation of propargylic alcohols: an efficient approach to alkenyl nitriles[J]. ORGANIC & BIOMOLECULAR CHEMISTRY,2014,12(25):4324-4328.
APA Huang, Xiaoqiang,&Jiao, Ning.(2014).Bronsted acid mediated nitrogenation of propargylic alcohols: an efficient approach to alkenyl nitriles.ORGANIC & BIOMOLECULAR CHEMISTRY,12(25),4324-4328.
MLA Huang, Xiaoqiang,et al."Bronsted acid mediated nitrogenation of propargylic alcohols: an efficient approach to alkenyl nitriles".ORGANIC & BIOMOLECULAR CHEMISTRY 12.25(2014):4324-4328.
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