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学科主题: 药学
题名:
Bronsted acid mediated nitrogenation of propargylic alcohols: an efficient approach to alkenyl nitriles
作者: Huang, Xiaoqiang1; Jiao, Ning1,2
刊名: ORGANIC & BIOMOLECULAR CHEMISTRY
发表日期: 2014
DOI: 10.1039/c4ob00888j
卷: 12, 期:25, 页:4324-4328
收录类别: SCI ; IC ; CCR
文章类型: Article
WOS标题词: Science & Technology
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
关键词[WOS]: MEYER-SCHUSTER REARRANGEMENT ; ONE-POT SYNTHESIS ; CARBONYL-COMPOUNDS ; ALPHA,BETA-UNSATURATED NITRILES ; STEREOSELECTIVE-SYNTHESIS ; PRACTICAL SYNTHESIS ; DIRECT TRANSFORMATION ; ALLENYL AZIDES ; BOND FORMATION ; CATALYSIS
英文摘要:

A novel and efficient approach to alkenyl nitriles from readily available propargylic alcohols has been developed. This nitrogenation reaction is transition-metal-free and could be conducted under air at ambient temperature, which makes this protocol promising and practical. Moreover, NH4Br is disclosed as an efficient additive to promote the stereoselectivity of this reaction.

语种: 英语
所属项目编号: 21325206 ; 21172006 ; 20120001110013
项目资助者: National Science Foundation of China ; National Young Topnotch Talent Support Program ; Ph.D. Programs Foundation of the Ministry of Education of China
WOS记录号: WOS:000337129000009
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.bjmu.edu.cn/handle/400002259/66334
Appears in Collections:北京大学药学院_期刊论文

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作者单位: 1.Peking Univ, Sch Pharmaceut Sci, State Key Lab Nat & Biomimet Drugs, Beijing 100191, Peoples R China
2.Nankai Univ, State Key Lab Elementoorgan Chem, Tianjin 300071, Peoples R China

Recommended Citation:
Huang, Xiaoqiang,Jiao, Ning. Bronsted acid mediated nitrogenation of propargylic alcohols: an efficient approach to alkenyl nitriles[J]. ORGANIC & BIOMOLECULAR CHEMISTRY,2014,12(25):4324-4328.
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