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PdCl2 catalyzed efficient assembly of organic azides, CO, and alcohols under mild conditions: a direct approach to synthesize carbamates
Ren, Long1; Jiao, Ning1,2
刊名CHEMICAL COMMUNICATIONS
2014
DOI10.1039/c4cc00538d
50期:28页:3706-3709
收录类别SCI ; IC ; CCR
文章类型Article
WOS标题词Science & Technology
类目[WOS]Chemistry, Multidisciplinary
研究领域[WOS]Chemistry
关键词[WOS]FUSED-HETEROCYCLIC-COMPOUNDS ; OXIDATIVE CARBONYLATION ; CURTIUS REARRANGEMENT ; NITRENE TRANSFER ; THERAPEUTIC EFFICACY ; N-TOSYLHYDRAZONES ; TRANSITION-METALS ; CARBOXYLIC-ACIDS ; CARBON-MONOXIDE ; ARYL HALIDES
英文摘要

A simple and readily available PdCl2 catalyzed carbamate synthesis method via isocyanate generation and application in situ has been developed. This chemistry provides an efficient and practical approach to synthesize carbamates from simple organic azides, CO atmosphere and alcohols. The broad scope, mild and neutral conditions, and only N-2 as the byproduct make this transformation very useful. Moreover, simple examples of modification of bioactivemolecules and construction of macrocycles were achieved through this protocol.

语种英语
WOS记录号WOS:000332927500015
引用统计
被引频次:28[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.bjmu.edu.cn/handle/400002259/66502
专题北京大学药学院
北京大学药学院_天然药物与仿生药物国家重点实验室
作者单位1.Peking Univ, Sch Pharmaceut Sci, State Key Lab Nat & Biomimet Drugs, Beijing 100191, Peoples R China
2.Nankai Univ, State Key Lab Elementoorgan Chem, Tianjin 300071, Peoples R China
推荐引用方式
GB/T 7714
Ren, Long,Jiao, Ning. PdCl2 catalyzed efficient assembly of organic azides, CO, and alcohols under mild conditions: a direct approach to synthesize carbamates[J]. CHEMICAL COMMUNICATIONS,2014,50(28):3706-3709.
APA Ren, Long,&Jiao, Ning.(2014).PdCl2 catalyzed efficient assembly of organic azides, CO, and alcohols under mild conditions: a direct approach to synthesize carbamates.CHEMICAL COMMUNICATIONS,50(28),3706-3709.
MLA Ren, Long,et al."PdCl2 catalyzed efficient assembly of organic azides, CO, and alcohols under mild conditions: a direct approach to synthesize carbamates".CHEMICAL COMMUNICATIONS 50.28(2014):3706-3709.
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