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学科主题: 药学
题名:
Improved synthesis of phytosphingosine and dihydrosphingosine from 3,4,6-tri-O-benzyl-D-galactal
作者: Niu, Youhong2; Cao, Xiaoping2; Ye, Xin-Shan1
刊名: HELVETICA CHIMICA ACTA
发表日期: 2008
卷: 91, 期:4, 页:746-752
收录类别: SCI ; IC ; CCR
文章类型: Article
WOS标题词: Science & Technology
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
关键词[WOS]: PROTEIN-KINASE-C ; ALPHA-GALACTOSYLCERAMIDE KRN7000 ; BIOLOGICALLY-ACTIVE GLYCOSIDES ; SACCHAROMYCES-CEREVISIAE ; HEPATIC METASTASIS ; SYMBIODINIUM-SP ; NKT CELLS ; STEREOCHEMISTRY ; ANTITUMOR ; MICE
英文摘要:

An efficient and facile synthesis of phytosphingosine and dihydrosphingosine derivatives is described with less steps and in improved overall yield (66-72%) starting from commercially available tri-O-benzyl-D-galactal. The key steps include Wittig reaction, Mitsunobu transformation, reduction, and deprotection.

语种: 英语
WOS记录号: WOS:000255731700015
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.bjmu.edu.cn/handle/400002259/66804
Appears in Collections:北京大学药学院_期刊论文

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作者单位: 1.Peking Univ, Sch Pharmaceut Sci, State Key Lab Nat & Biomimet Drugs, Beijing 100083, Peoples R China
2.Lanzhou Univ, Coll Chem & Chem Engn, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China

Recommended Citation:
Niu, Youhong,Cao, Xiaoping,Ye, Xin-Shan. Improved synthesis of phytosphingosine and dihydrosphingosine from 3,4,6-tri-O-benzyl-D-galactal[J]. HELVETICA CHIMICA ACTA,2008,91(4):746-752.
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