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学科主题: 药学
题名:
One-Pot AgOAc-Mediated Synthesis of Polysubstituted Pyrroles from Primary Amines and Aldehydes: Application to the Total Synthesis of Purpurone
作者: Li, Qingjiang1; Fan, Aili1; Lu, Zhiyao1; Cui, Yuxin1; Lin, Wenhan1; Jia, Yanxing1,2
刊名: ORGANIC LETTERS
发表日期: 2010-09-17
DOI: 10.1021/ol101644g
卷: 12, 期:18, 页:4066-4069
收录类别: SCI ; IC ; CCR
文章类型: Article
WOS标题词: Science & Technology
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
关键词[WOS]: EFFICIENT TOTAL-SYNTHESIS ; C BOND FORMATION ; N-ARYL ENAMINES ; LEAD-TETRAACETATE ; SUBSTITUTED PYRROLES ; SEQUENTIAL REACTIONS ; COUPLING REACTIONS ; DIRECT ANNULATION ; ALPHA-ARYLATION ; OXIDATION
英文摘要:

A simple and efficient method for the synthesis of 1,3,4-trisubstituted or 3,4-disubstituted pyrroles has been developed. The reaction represents the first time that pyrroles are synthesized directly from readily available aldehydes and amines (anilines) as starting materials. This method has been successfully applied to the rapid synthesis of purpurone.

语种: 英语
所属项目编号: 2010CB833200 ; 20972007 ; 20802005 ; 30930109
项目资助者: National Basic Research Program of China (973 Program) ; State Key Laboratory of Drug Research ; National Natural Science Foundation of China ; NCET
WOS记录号: WOS:000281596800027
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.bjmu.edu.cn/handle/400002259/67173
Appears in Collections:北京大学药学院_期刊论文

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作者单位: 1.Peking Univ, State Key Lab Nat & Biomimet Drugs, Sch Pharmaceut Sci, Beijing 100191, Peoples R China
2.Chinese Acad Sci, State Key Lab Drug Res, Shanghai Inst Mat Med, Shanghai 201203, Peoples R China

Recommended Citation:
Li, Qingjiang,Fan, Aili,Lu, Zhiyao,et al. One-Pot AgOAc-Mediated Synthesis of Polysubstituted Pyrroles from Primary Amines and Aldehydes: Application to the Total Synthesis of Purpurone[J]. ORGANIC LETTERS,2010,12(18):4066-4069.
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