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One-Pot AgOAc-Mediated Synthesis of Polysubstituted Pyrroles from Primary Amines and Aldehydes: Application to the Total Synthesis of Purpurone
Li, Qingjiang1; Fan, Aili1; Lu, Zhiyao1; Cui, Yuxin1; Lin, Wenhan1; Jia, Yanxing1,2
刊名ORGANIC LETTERS
2010-09-17
DOI10.1021/ol101644g
12期:18页:4066-4069
收录类别SCI ; IC ; CCR
文章类型Article
WOS标题词Science & Technology
类目[WOS]Chemistry, Organic
研究领域[WOS]Chemistry
关键词[WOS]EFFICIENT TOTAL-SYNTHESIS ; C BOND FORMATION ; N-ARYL ENAMINES ; LEAD-TETRAACETATE ; SUBSTITUTED PYRROLES ; SEQUENTIAL REACTIONS ; COUPLING REACTIONS ; DIRECT ANNULATION ; ALPHA-ARYLATION ; OXIDATION
英文摘要

A simple and efficient method for the synthesis of 1,3,4-trisubstituted or 3,4-disubstituted pyrroles has been developed. The reaction represents the first time that pyrroles are synthesized directly from readily available aldehydes and amines (anilines) as starting materials. This method has been successfully applied to the rapid synthesis of purpurone.

语种英语
WOS记录号WOS:000281596800027
项目编号2010CB833200 ; 20972007 ; 20802005 ; 30930109
资助机构National Basic Research Program of China (973 Program) ; State Key Laboratory of Drug Research ; National Natural Science Foundation of China ; NCET
引用统计
被引频次:74[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.bjmu.edu.cn/handle/400002259/67173
专题北京大学药学院
作者单位1.Peking Univ, State Key Lab Nat & Biomimet Drugs, Sch Pharmaceut Sci, Beijing 100191, Peoples R China
2.Chinese Acad Sci, State Key Lab Drug Res, Shanghai Inst Mat Med, Shanghai 201203, Peoples R China
推荐引用方式
GB/T 7714
Li, Qingjiang,Fan, Aili,Lu, Zhiyao,et al. One-Pot AgOAc-Mediated Synthesis of Polysubstituted Pyrroles from Primary Amines and Aldehydes: Application to the Total Synthesis of Purpurone[J]. ORGANIC LETTERS,2010,12(18):4066-4069.
APA Li, Qingjiang,Fan, Aili,Lu, Zhiyao,Cui, Yuxin,Lin, Wenhan,&Jia, Yanxing.(2010).One-Pot AgOAc-Mediated Synthesis of Polysubstituted Pyrroles from Primary Amines and Aldehydes: Application to the Total Synthesis of Purpurone.ORGANIC LETTERS,12(18),4066-4069.
MLA Li, Qingjiang,et al."One-Pot AgOAc-Mediated Synthesis of Polysubstituted Pyrroles from Primary Amines and Aldehydes: Application to the Total Synthesis of Purpurone".ORGANIC LETTERS 12.18(2010):4066-4069.
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