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学科主题药学
Protecting Groups in Carbohydrate Chemistry: Influence on Stereoselectivity of Glycosylations
Guo, Jian; Ye, Xin-Shan
关键词protecting group stereoselectivity glycosylation carbohydrate
刊名MOLECULES
2010-10-01
DOI10.3390/molecules15107235
15期:10页:7235-7265
收录类别SCI
文章类型Review
WOS标题词Science & Technology
类目[WOS]Chemistry, Organic
研究领域[WOS]Chemistry
关键词[WOS]NEIGHBORING-GROUP PARTICIPATION ; ALPHA-SELECTIVE GLYCOSYLATIONS ; PRE-ACTIVATION PROTOCOL ; N-PENTENYL GLYCOSIDES ; OLIGOSACCHARIDE SYNTHESIS ; ONE-POT ; BETA-MANNOPYRANOSYLATION ; STEREOCONTROLLED SYNTHESIS ; PREACTIVATION PROTOCOL ; RADICAL FRAGMENTATION
英文摘要

Saccharides are polyhydroxy compounds, and their synthesis requires complex protecting group manipulations. Protecting groups are usually used to temporarily mask a functional group which may interfere with a certain reaction, but protecting groups in carbohydrate chemistry do more than protecting groups usually do. Particularly, protecting groups can participate in reactions directly or indirectly, thus affecting the stereochemical outcomes, which is important for synthesis of oligosaccharides. Herein we present an overview of recent advances in protecting groups influencing stereoselectivity in glycosylation reactions, including participating protecting groups, and conformation-constraining protecting groups in general.

语种英语
WOS记录号WOS:000283587400041
引用统计
被引频次:59[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.bjmu.edu.cn/handle/400002259/67477
专题北京大学药学院
北京大学药学院_药物化学系
作者单位Peking Univ, State Key Lab Nat & Biomimet Drugs, Sch Pharmaceut Sci, Beijing 100191, Peoples R China
推荐引用方式
GB/T 7714
Guo, Jian,Ye, Xin-Shan. Protecting Groups in Carbohydrate Chemistry: Influence on Stereoselectivity of Glycosylations[J]. MOLECULES,2010,15(10):7235-7265.
APA Guo, Jian,&Ye, Xin-Shan.(2010).Protecting Groups in Carbohydrate Chemistry: Influence on Stereoselectivity of Glycosylations.MOLECULES,15(10),7235-7265.
MLA Guo, Jian,et al."Protecting Groups in Carbohydrate Chemistry: Influence on Stereoselectivity of Glycosylations".MOLECULES 15.10(2010):7235-7265.
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