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学科主题: 药学
题名:
Mn-promoted Aerobic Oxidative C-C Bond Cleavage of Aldehydes with Dioxygen Activation: A Simple Synthetic Approach to Formamides
作者: Zhang, Chun1,2; Xu, Zejun1,2; Shen, Tao1,2; Wu, Guolin1,2; Zhang, Liangren1,2; Jiao, Ning1,2,3
刊名: ORGANIC LETTERS
发表日期: 2012-05-04
DOI: 10.1021/ol300781s
卷: 14, 期:9, 页:2362-2365
收录类别: SCI ; IC ; CCR
文章类型: Article
WOS标题词: Science & Technology
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
关键词[WOS]: CARBON-CARBON BONDS ; MOLECULAR-OXYGEN ; CATALYZED OXIDATION ; OXIDASE CATALYSIS ; ALPHA-KETOAMIDES ; COPPER ; PALLADIUM ; AMINES ; DERIVATIVES ; COMPLEXES
英文摘要:

A novel Mn-promoted aerobic oxidative C-C bond cleavage of aldehydes with dioxygen activation has been developed. The usage of molecular oxygen (1 atm) as oxidant, reactant, and an initiator to trigger this transformation makes this transformation very green and practical. A plausible radical process is proposed on the basis of mechanistic studies. Furthermore, this method provides a practical, neutral, and mild synthetic approach to formamides, which are important units in biologically active molecules.

语种: 英语
所属项目编号: 2009CB825300 ; 20872003 ; 21172006
项目资助者: National Basic Research Program of China (973 Program) ; National Science Foundation of China
WOS记录号: WOS:000303492200044
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.bjmu.edu.cn/handle/400002259/68258
Appears in Collections:北京大学药学院_期刊论文

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作者单位: 1.Peking Univ, State Key Lab Nat & Biomimet Drugs, Beijing 100191, Peoples R China
2.Peking Univ, Sch Pharmaceut Sci, Beijing 100191, Peoples R China
3.Chinese Acad Sci, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

Recommended Citation:
Zhang, Chun,Xu, Zejun,Shen, Tao,et al. Mn-promoted Aerobic Oxidative C-C Bond Cleavage of Aldehydes with Dioxygen Activation: A Simple Synthetic Approach to Formamides[J]. ORGANIC LETTERS,2012,14(9):2362-2365.
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