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Mn-promoted Aerobic Oxidative C-C Bond Cleavage of Aldehydes with Dioxygen Activation: A Simple Synthetic Approach to Formamides
Zhang, Chun1,2; Xu, Zejun1,2; Shen, Tao1,2; Wu, Guolin1,2; Zhang, Liangren1,2; Jiao, Ning1,2,3
刊名ORGANIC LETTERS
2012-05-04
DOI10.1021/ol300781s
14期:9页:2362-2365
收录类别SCI ; IC ; CCR
文章类型Article
WOS标题词Science & Technology
类目[WOS]Chemistry, Organic
资助者National Basic Research Program of China (973 Program) ; National Science Foundation of China ; National Basic Research Program of China (973 Program) ; National Science Foundation of China
研究领域[WOS]Chemistry
关键词[WOS]CARBON-CARBON BONDS ; MOLECULAR-OXYGEN ; CATALYZED OXIDATION ; OXIDASE CATALYSIS ; ALPHA-KETOAMIDES ; COPPER ; PALLADIUM ; AMINES ; DERIVATIVES ; COMPLEXES
英文摘要

A novel Mn-promoted aerobic oxidative C-C bond cleavage of aldehydes with dioxygen activation has been developed. The usage of molecular oxygen (1 atm) as oxidant, reactant, and an initiator to trigger this transformation makes this transformation very green and practical. A plausible radical process is proposed on the basis of mechanistic studies. Furthermore, this method provides a practical, neutral, and mild synthetic approach to formamides, which are important units in biologically active molecules.

语种英语
所属项目编号2009CB825300 ; 20872003 ; 21172006
资助者National Basic Research Program of China (973 Program) ; National Science Foundation of China ; National Basic Research Program of China (973 Program) ; National Science Foundation of China
WOS记录号WOS:000303492200044
Citation statistics
Cited Times:58[WOS]   [WOS Record]     [Related Records in WOS]
文献类型期刊论文
条目标识符http://ir.bjmu.edu.cn/handle/400002259/68258
Collection北京大学药学院
作者单位1.Peking Univ, State Key Lab Nat & Biomimet Drugs, Beijing 100191, Peoples R China
2.Peking Univ, Sch Pharmaceut Sci, Beijing 100191, Peoples R China
3.Chinese Acad Sci, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
Recommended Citation
GB/T 7714
Zhang, Chun,Xu, Zejun,Shen, Tao,et al. Mn-promoted Aerobic Oxidative C-C Bond Cleavage of Aldehydes with Dioxygen Activation: A Simple Synthetic Approach to Formamides[J]. ORGANIC LETTERS,2012,14(9):2362-2365.
APA Zhang, Chun,Xu, Zejun,Shen, Tao,Wu, Guolin,Zhang, Liangren,&Jiao, Ning.(2012).Mn-promoted Aerobic Oxidative C-C Bond Cleavage of Aldehydes with Dioxygen Activation: A Simple Synthetic Approach to Formamides.ORGANIC LETTERS,14(9),2362-2365.
MLA Zhang, Chun,et al."Mn-promoted Aerobic Oxidative C-C Bond Cleavage of Aldehydes with Dioxygen Activation: A Simple Synthetic Approach to Formamides".ORGANIC LETTERS 14.9(2012):2362-2365.
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